[Ir(bpy)(dfppy)2]PF6

Catalog Number

864163-80-4

CAS

864163-80-4

Synonyms

Bis[2-(2,4-difluorophenyl)pyridine][2-2'-bipyridine] iridium(III) hexafluorophosphate; (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate; Iridium(1+), (2,2'-bipyridine-κN1,κN1')bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1)

Application

Transition Metal Catalysts

Molecular Weight

873.70

Molecular Formula

C32H20F4IrN4.F6P

Product Information

Purity

≥95%

Physical State

Solid

Appearance

Light Yellow to Brown Powder to Crystal

Storage

Store at RT under inert atmosphere

Melting Point

250°C

Safety Information

Signal Word

Warning

Precautionary Statement

P264 : Wash skin thoroughly after handling.P280 : Wear protective gloves/ eye protection/ face protection.P337 + P313 : If eye irritation persists: Get medical advice/ attention.P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.P332 + P313 : If skin irritation occurs: Get medical advice/ attention.P362 : Take off contaminated clothing and wash before reuse.

Hazard Statements

H315 : Causes skin irritation.H319 : Causes serious eye irritation.

Canonical SMILES

FC=1C=C(F)C=2C=3C=CC=C[N]3[Ir+3]45([C-]2C1)([C-]=6C=C(F)C=C(F)C6C=7C=CC=C[N]74)[N]=8C=CC=CC8C=9C=CC=C[N]95.[F-][P+5]([F-])([F-])([F-])([F-])[F-]

InChI

InChI=1S/2C11H6F2N.C10H8N2.F6P.Ir/c2*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-7(2,3,4,5)6;/h2*1-4,6-7H;1-8H;;/q2*-1;;-1;+3

InChI Key

BWQRXIXHHHVGJD-UHFFFAOYSA-N