Bis(triphenylphosphine)nickel(II)chloride

Ordering Information

Catalog Number Size Price Stock Quantity
B1370-364903 1 kg $499 In stock
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Product Information

Catalog Number
B1370-364903
CAS
14264-16-5
IUPAC Name
dichloronickel;bis(triphenylphosphane)
Synonyms
Nickel, dichlorobis(triphenylphosphine)-; Bis(tri-N-butylphosphine)dichloronickel; Dichlorobis(triphenyIphosphine)-nickel(II)
Application
Ni(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.
Molecular Weight
654.17
Molecular Formula
C36H30Cl2NiP2
structural: Bis(triphenylphosphine)nickel(II)chloride

Product Information

Purity
98%
MDL
MFCD00009592
Appearance
Dark Green to Dark Gray Crystals
Storage
Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
Melting Point
250 °C (dec.)(lit.)
Flash Point
Not applicable
Solubility
Soluble in DMSO (Slightly), Methanol (Slightly)

Safety Information

Signal Word
Danger
Precautionary Statement
P501 P272 P260 P270 P202 P201 P264 P280 P284 P302 + P352 P308 + P313 P362+P364 P304 + P340 P333 + P313 P301 + P312 + P330 P405
Hazard Statements
H317-H350-H412
Hazard Class
6.1(b)
WGK Germany
3
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Ni]Cl
InChI
InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI Key
ZBRJXVVKPBZPAN-UHFFFAOYSA-L

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