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Bis(triphenylphosphine)nickel(II) dichloride
Catalog Number
14264-16-5
CAS
14264-16-5
IUPAC Name
dichloronickeltriphenylphosphane
Synonyms
Dichlorobis(triphenylphosphine)nickel(II),NiCl2(PPh3)2,Nickel(II)bis(triphenylphosphine) dichloride
Application
Ni(PPh3)2Cl2 may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.
Molecular Weight
654.17
Molecular Formula
[(C6H5)3P]2NiCl2
Product Information
Purity
0.9999
MDL
MFCD00009592
Appearance
Dark green to Dark blue to Black powder to crystal
Storage
Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.
Melting Point
250 °C (dec.) (lit.)
Flash Point
Not applicable
Safety Information
Signal Word
Danger
Precautionary Statement
P501 P272 P260 P270 P202 P201 P264 P280 P284 P302 + P352 P308 + P313 P362+P364 P304 + P340 P333 + P313 P301 + P312 + P330 P405
Hazard Statements
H317-H350-H412
Hazard Class
6.1(b)
WGK Germany
3
Canonical SMILES
Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI
InChI=1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h2*1-15H2*1H/q+2/p-2
InChI Key
ZBRJXVVKPBZPAN-UHFFFAOYSA-L
